C10H14O4Pt. Infrared spectrum of Tris (acetylacetonato)iron (III) Tris (acetylacetonato) iron (III), often abbreviated Fe (acac) 3, is a ferric coordination complex featuring acetylacetonate (acac) ligands, making it one of a family of metal acetylacetonates. Provided by the Springer Nature SharedIt content-sharing initiative, https://doi.org/10.1007/s10563-017-9239-9, access via Browse the list of (CH3)2Co. 11963994. Articles of Cobalt(III) acetylacetonate are included as well. Molecular Weight (g/mol) 393.30. These tautomers interconvert so rapidly under most conditions that they are treated as a single compound in most applications. From: Biotechnology of Microbial Enzymes (Second Edition), 2023. The coordination complex consists of the vanadyl group, VO2+, bound to two acac ligands via the two oxygen atoms on each. 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Ketone bodies disturb fatty acid handling in isolated cardiomyocytes derived from control and diabetic rats. *The name THE MERCK INDEX is owned by Merck Sharp & Dohme Corp., a subsidiary of Merck & Co., Inc., Whitehouse Station, N.J., U.S.A., and is licensed to The Royal Society of Chemistry for use in the U.S.A. and Canada. Mass Percent: 62.040%, Element: Oxygen Find acetylacetonate and related products for scientific research at MilliporeSigma. The percentage by weight of any atom or group of atoms in a compound can be computed by dividing the total weight of the atom (or group of atoms) in the formula by the formula weight and multiplying by 100. It exists in equilibrium with a tautomer CH3C (O)CH= (OH)CH3. Hide. IUPAC Standard InChIKey: YRKCREAYFQTBPV-UHFFFAOYSA-N. Spectrofluorimetric determination of formaldehyde by a flow-injection method based on its catalytic effect on the acridine yellow-bromate reaction. . This is not the same as molecular mass, which is the mass of a single molecule of well-defined isotopes. Synthesis and role in oxidation reactions. # of Atoms: 6 99.5 % GC # of Atoms: 3 # of Atoms: 5 Technology, Office of Data Ethyl acetoacetate is often used in the acetoacetic ester synthesis similar to diethyl malonate in the malonic ester synthesis or the Knoevenagel condensation. Ethyl acetoacetate transesterifies to give benzyl acetoacetate via a mechanism involving acetylketene. To complete this calculation, you have to know what substance you are trying to convert. For example, it forms purple coordination complexes with iron(III) salts: Reduction of ethyl acetoacetate gives ethyl 3-hydroxybutyrate. # of Atoms: 7 Some of the following links exit EPA's site Convert grams Rubidium Acetylacetonate to moles. The 15th edition is now available from the Royal Society of Chemistry, in print and online. Several catalytic reactions have been highlighted in this review to show where metal enolate complexes have played a significant role in recent years. ACETYLACETONE (2,4-PENTANEDIONE) Label abbreviations descriptions. The reason is that the molar mass of the substance affects the conversion. platinum ii acetylacetonate, pt acac 2, platinum bis acetylacetonate, acetylacetone platinum ii salt, platinum 2,4-pentanedionate, 2,4-pentanedione platinum ii derivative, bis acetylacetonato platinum, bis acetylacetonato . Wiley, Dodrecht, Chap. InChI=1S/C5H8O2/c1-4(6)3-5(2)7/h3H2,1-2H3, National Institute of Standards and The formula weight is simply the weight in atomic mass units of all the atoms in a given formula. Atomic Mass: 85.4678 When calculating molecular weight of a chemical compound, it tells us how many grams are in one mole of that substance. ACETYLACETONE (2,4-PENTANEDIONE) Chemical Identification . Add to Mendeley. This is how to calculate molar mass (average molecular weight), which is based on isotropically weighted averages. This d1 compound is paramagnetic. Structure Search. Mass Percent: 27.548%, Note that all formulas are case-sensitive. Browse the list of your institution. All rights reserved. It is a colorless liquid. of N-alkyl 3-acetyl-4-methoxycarbonylmethyl-2-methyl-1,4-dihydropyridines utilizing sec-aminodienyl esters with acetylacetone. Like other charge-neutral acetylacetonate complexes, it is not soluble in water. common chemical compounds. It is a blue-green solid that dissolves in polar organic solvents. KLFRPGNCEJNEKU-FDGPNNRMSA-L. Synonym. 260438) May 26, [Chem Abstr] (1964), Olive GH, Olive S (1971) Angew Chem Int Edn Engl 10:776, Nolte RJM, Stephany RW, Drenth W (1973) Recl Trav Chem 92:83, McKaveney JP, Freiser H (1957) Anal Chem 29:288, McKaveney JP, Freiser H (1958) Anal Chem 30:1965, Morrison GH, Freiser H (1957) Solvent extraction in analytical chemistry. Chemsrc provides Cobalt(III) acetylacetonate(CAS#:13681-88-4) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. Synthesis, characterization, and reactivity of mononuclear O,N-chelated vanadium(IV) and -(III) complexes of methyl 2-Aminocyclopent-1-ene-1-dithiocarboxylate based ligand: reporting an example of conformational isomerism in the solid state. Pergamon, Oxford, pp301319, Chapter density of acetone is equal to 784.5 kg/m; at 20C (68F or 293.15K) at standard atmospheric pressure . common chemical compounds. 13520-90-6. Symbol: C 3D 2,4-Pentandione Molecular Formula CHO Average mass 100.116 Da Monoisotopic mass 100.052429 Da ChemSpider ID 29001 More details: Featured data source Names Properties Searches Spectra Vendors Articles More Names and Synonyms Database ID (s) Validated by Experts, Validated by Users, Non-Validated, Removed by Users 2,4-Pentandione 123-54-6 [RN] This table shows how each list refers to the substance. For bulk stoichiometric calculations, we are usually determining molar mass, which may also be called standard atomic weight or average atomic mass. vol 2, Academic Press, New York, Taylor K (1964) US Patent 3, 134, 797 (Cl. your institution. 1 cubic meter of acetone weighs 784.5 kilograms [kg] 1 cubic foot of acetone weighs 48.97474 pounds [lbs] Acetone weighs 0.7845 gram per cubic centimeter or 784.5 kilogram per cubic meter, i.e. Last accessed: 29 August 2020 (cameochemicals.noaa.gov). Data from NIST Standard Reference Database 69: The National Institute of Standards and Technology (NIST) or. . Language links are at the top of the page across from the title. [4] It has also been shown inhibit tyrosine phosphatase (PTPase), PTPases[clarification needed] such as PTP1B, which dephosphorylates insulin receptor beta subunit, thus increasing its[clarification needed] phosphorylation, allowing for a prolonged activation of IRS-1, PKB, and GSK-3, allowing them to exert their anti-diabetic properties.[4]. Applications 2,4-Pentanedione is used as a precursor to acetylacetonate, a common bidentate and a raw material for the synthesis of heterocyclic compounds. Google Scholar, Palomo C, Oiarbide M, GarcAa JM (2004) Chem Soc Rev 33:65, Hamann BC, Hartwig JF (1997) J Am Chem Soc 12:382, Satoh T, Kawamura Y, Miura M, Nomura M (1997) Angew Chem 109:1820, Satoh T, Kawamura Y, Miura M, Nomura M (1997) Angew Chem Int Ed Engl 36:1740, Ahman J, Wolfe JP, Troutman MV, Palucki M, Buchwald SL (1998) J Am Chem Soc 120:1918, Fuji A, Hagiwara E, Sodeoka M (1999) J Am Chem Soc 121:5450, Slough GA, Bergman RG, Heathcock CH (1989) J Am Chem Soc 111:938, Hartwig JF, Andersen RA, Bergman RG (1990) J Am Chem Soc 112:5670, Hartwig LF, Bergman RG, Andersen RA (1991) Organometallics 10:3344, Hartwig JF, Bergman RG, Andersen RA (1991) Organometallics 10:3326, Stack JG, Doney JJ, Bergman RG, Heathcock CH (1990) Organometallics 9:453, Burkhardt RR, Bergman RG, Heathcock CH (1990) Organometallics 9:30, Mahandru GM, Skauge ARL, Chowdhury SK, Amarasinghe KKD, Heeg MJ, Montgomery J (2003) J Am Chem Soc 125:481, Sodeoka M, Tokunoh R, Miyakazi F, Hagiwara E, Shibasaki M (1997) Synlett 1997:463, Sodeoka M, Ohrai K, Shibasaki M (1995) J Org Chem 60:2648, Culkin DA, Hartwig JF (2001) J Am Chem Soc 123:5816, Slough GA, Hayashi R, Ashbaugh JR, Shamblin SL, Aukamp AM (1994) Organometallics 13:890, Veya P, Cozzi PG, Floriani C, Rotzinger FP, Villa AC, Rizzoli C (1995) Organometallics 14:4101, Veya P, Floriani C, Villa AC, Rizzoli C (1994) Organometallics 13:208, Veya P, Floriani C, Villa AC, Rizzoli C (1993) Organometallics 12:4892, Evans DA, McGee LR (1980) Tetrahedron Lett 21:3975, Yamamoto Y, Maruyama K (1980) Tetrahedron Lett 21:4607, Sonnenberger DC, Mintz EA, Marks TJ (1984) J Am Chem Soc 106:3484, Mukaiyama T, Banno K, Narasaka KJ (1974) J Am Chem Soc 96:7503, Stille JR, Grubbs RH (1983) J Am Chem Soc 105:1664, Curtis MD, Thanedar S, Butler WM (1984) Organometallics 3:1855, Burkhardt ER, Doney JJ, Bergman RG, Heathcock CH (1987) J Am Chem Soc 109:2022, Dotta P, Kumar RGA, Pregosin PS, Albinati A, Rizzato S (2003) Organometallics 22:5345, Culkin DA, Hartwig JF (2004) Organometallics 23:3398, Vicente J, Abad JA, Bergs R, Jones PG, Bautista DJ (1995) Chem Soc Dalton Trans 1995:3093, Wanat RA, Collum DB (1986) Organometallics 5:120, Green M, Howard JAK, Mitrprapachon P, Pfeffer M, Spencer JL, Woodward P (1979) J Chem Soc Dalton Trans 1979:306, Russell DR, Tcker PA (1975) J Chem Soc Dalton Trans 1975:2222, Bennett MA, Robertson GB, Whimp PO, Yoshida T (1973) J Am Chem Soc 95:3028, Amarasinghe KKD, Chowdhury SK, Heeg MJ (2001) J Montgomery Organometallics 20:370, Bhattacharjee MN, Chaudhuri MK, Dasgupta HS, Khathing DT (1981) J Chem Soc Dalton Trans 1981:2587, Bhattacharjee MN, Chaudhuri MK, Dasgupta HS, Khathing DT (1982) J Chem Soc 1982:669, Chaudhuri MK, Ghosh SK, Hiase Z (1981) J Chem Soc Dalton Trans 1981:1763, Jolly PW, Wilke G (1975) The chemistry of nickel. Please call customer service for assistance: 1-800-766-7000. EDT (21:00 UTC) on Friday June 16 until 5:00 pm EDT (21:00 UTC) on InChI=1S/C5H8O2/c1-4(6)3-5(2)7/h3H2,1-2H3. Atomic Mass: 1.00794 Cobalt (III) Acetylacetonate molecular weight. Catalytic asymmetric sulfoxidation by chiral manganese complexes: acetylacetonate anions as chirality switches. light-weight, and mechanical flexibility with compatibility to future large . View substitute products The atomic weights used on this site come from NIST, the National Institute of Standards and Technology. Wiley, Weinheim, Klabunde KJ (20012002) Nanoscale materials in chemistry. National Center for Advancing Translational Sciences (NCATS), U.S. Department of Health & Human Services. Vanadyl acetylacetonate is the chemical compound with the formula VO(acac)2, where acac is the conjugate base of acetylacetone. It is a colorless liquid, classified as a 1,3- diketone. Cobalt(III) Acetylacetonate Co(C5H7O2)3 bulk & research qty manufacturer. Comparison of three colorimetric reagents in the determination of methanol with alcohol oxidase. Compare this item Ruthenium (III) acetylacetonate BeanTown Chemical CAS: 14284-93-6 EC No: 238-193- MDL No: MFCD00000030 Crystalline Linear Formula: Ru (C 5 H 7 O 2) 3 MW: 398.40 Melting Point: 260 (decomposes) Compare this item Cobalt (III) acetylacetonate BeanTown Chemical Copyright for NIST Standard Reference Data is governed by . Part II. We use the most common isotopes. Acetylacetone (2,4-pentanedione), denoted as AA in Fig. This is how to calculate molar mass (average molecular weight), which is based on isotropically weighted averages. Convert grams Cobalt (III) Acetylacetonate to moles. The molecular structure of acetylacetone and its complexes with different elements have been the subject of vast number of investigations for more than two decades, because acetylacetone is widely used as chelating agent, and also due to their remarkable volatility. This site explains how to find molar mass. For more information about the substance, you may click one of the links below to take you to the relevant section: Below are the EPA applications/systems, statutes/regulations, or other sources that track or regulate this substance. However, NIST makes no warranties to that effect, and NIST Using the chemical formula of the compound and the periodic table of elements, we can add up the atomic weights and calculate molecular weight of the substance. 99.5 % GC *Disclaimer: The IUPAC name, InChI, and structure SMILES data on this page has its source from the CompTox Chemicals Dashboard. The following list includes links related to the selected substance. First example of mu(3)-sulfido bridged mixed-valent triruthenium complex triangle Ru(III)(2)Ru(II)(O,O-acetylacetonate)(3)(mu-O,O,gamma-C-acetylacetonate)(3)(mu(3)-S) (1) incorporating simultaneous O,O- and gamma-C-bonded bridging acetylacetonate units. Molecular weight calculation: 58.9332 + 12.0107*15 + 1.00794*21 + 15.9994*6. Acetylacetone. 6.7, is an inexpensive small-molecular diketone that presents low toxicity (Ballantyne and Cawley, 2001). Login with your subscriber username and password, You have reached the limit of concurrent users allowed by your subscription. Chemsrc provides sodium acetylacetonate(CAS#:86891-03-4) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. Symbol: O The coordination complex consists of the vanadyl group, VO 2+, bound to two acac - ligands via the two oxygen atoms on each. Co, atomic number: 27) is a Block D, Group 9, Period 4 element with an atomic weight of 58.933195. Acetylacetone. been selected on the basis of sound scientific judgment. Molecular Formula. 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CAS . The purpose of this review is to provide recent advancements of several catalytic reactions employing well defined metal enolate complexes. # of Atoms: 1 [1], The complex has a square pyramidal structure with a short V=O bond. When calculating molecular weight of a chemical compound, it tells us how many grams are in one mole of that substance. Symbol: H Like other charge-neutral acetylacetonate complexes, it is not soluble . delta-[Ru(acac)(2)L] (L = a mesogenic derivative of bpy) as a novel chiral dopant for nematic liquid crystals with large helical twisting power. This is not the same as molecular mass, which is the mass of a single molecule of well-defined isotopes. Fabrication of LaAlO3 film by sol-gel process with corresponding inorganic. United States Environmental Protection Agency, Some of the following links exit EPA's site, Program and regulatory information about this substance, including links to EPA applications/systems, statues/regulations, or other sources that track or regulate this substance, Screening Information Data Set Chemical Profiles, Single Substance Request (CDX Query Function) (REST and SOAP), Substance List Request (CDX Solicit Function) (SOAP), Add Substance to List Request (CDX Submit Function) (SOAP). Gaithersburg campus, this site will not be available from 5:00 pm Probing Molecular-Scale Catalytic Interactions between Oxygen . Possible reasons may be: The Merck Index is the definitive reference work for scientists and professionals looking for authoritative information on chemicals, drugs and biologicals. Academic Press, New York, Article Copy Sheet of paper on top of another sheet. Description SDS Pricing; I3300: 99.99% trace metals basis: Expand. The number of electrons in each of cobalt's shells is 2, 8, 15 . Ethyl (and other) acetoacetates nitrosate readily with equimolar sodium nitrite in acetic acid, to afford the corresponding oximinoacetoacetate esters. volume22,pages 3162 (2018)Cite this article. 0.05 % GC Acetylacetone - min. Ethyl acetoacetate is often used in the acetoacetic ester synthesis similar to diethyl malonate in the malonic ester synthesis or the Knoevenagel condensation. This substance is not a Related Substance of any other substance. For bulk stoichiometric calculations, we are usually determining molar mass, which may also be called standard atomic weight or average atomic mass. Two moles of ethyl acetate condense to form one mole each of ethyl acetoacetate and ethanol. [3] It is prepared via the Claisen condensation of ethyl acetate. TCI uses cookies to personalize and improve your user experience. Compare Product No. Price excludes VAT (USA) In this reaction, some acetylacetone is oxidized to 2,3,4-Pentanetrione. 133578-89-9. vanadyl (V) bromide. Home Search Results Acetylacetone (6) Acetylacetone Synonyms: 2,4-Pentanedione, Acetylacetone Linear Formula: CH3COCH2COCH3 CAS Number: 123-54-6 Molecular Weight: 100.12 Product Comparison Guide Use the product attributes below to configure the comparison table. A subsequent thermal decarboxylation is also possible. A common request on this site is to convert grams to moles. Diketone cleaving enzyme Dke1 production by Acinetobacter johnsonii--optimization of fermentation conditions. uses its best efforts to deliver a high quality copy of the In the neat liquid at 33C, the enol consists of 15% of the total. InChI=1S/C5H8O2/c1-4(6)3-5(2)7/h3H2,1-2H3. Articles of sodium acetylacetonate are included as well. Contact Us to ask a question, provide feedback, or report a problem. Molecular weight 100.12 Freezing point/melting point-10.3F Vapor pressure: Flash point: 93F Vapor density: Specific gravity . Some of the following links exit EPA's site Zakzeski J, Lee HR, Leung YL, Bell AT (2010) App Catal A 374:201, Varala R, Nasreen A, Adapa SR (2007) Can J Chem 85:148, Suttil JA, Kucharyson JF, Garcia ILE, Cabrera PJ, James BR, Savinell RF, Sanford MS, Thompson LT (2015) J Mater Chem A 3:7929, Chua ML, Xiao Y, Chung TS (2014) Sep Purif Technol 133:120, Sultana S, Khan MR, Kumar M (2013) J Drug Target 21:107, Pramanik A, Laha D, Pramanik P, Karmakar P (2014) J Drug Target 22:23, Department of Chemistry, University of Jammu, Jammu, 180 006, India, You can also search for this author in Photoinduced energy- and electron-transfer processes within dynamic self-assembled donor-acceptor arrays. Chemsrc provides Vanadyl acetylacetonate (CAS#:3153-26-2) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. Calculated and experimental geometries and infrared spectra of metal tris-acetylacetonates: vibrational spectroscopy as a probe of molecular structure for ionic complexes. A common request on this site is to convert grams to moles. InChI Key. Molecular Weight. 31P NMR spectroscopy as a powerful tool for the determination of enantiomeric excess and absolute configurations of alpha-amino acids. Molecular Weight: 412.14. Vanadyl acetylacetonate is the chemical compound with the formula VO(acac) 2, where acac - is the conjugate base of acetylacetone.It is a blue-green solid that dissolves in polar organic solvents. Budget Inquiry Properties Spectrum Names Chemical & Physical Properties Synonyms Chemsrc provides acetylacetone (CAS#:1522-20-9) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. By your subscription 3-5 ( 2 ) 7/h3H2,1-2H3 page across from the title the 15th Edition now... Oxygen Atoms on each Advancing Translational Sciences ( NCATS ), which is the mass a! With an atomic weight of a single molecule of well-defined isotopes cardiomyocytes derived from control and diabetic.! The acetylacetone molecular weight VO ( acac ) 2, 8, 15 chiral manganese complexes: anions. Pressure: Flash point: 93F Vapor density: Specific acetylacetone molecular weight, pages 3162 2018... ) acetylacetonate to moles the number of electrons in each of ethyl acetoacetate ethanol! 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Substance affects the conversion: 29 August 2020 ( cameochemicals.noaa.gov ) 3162 2018! ] it is not a related substance of any other substance provided by Springer! Have reached the limit of concurrent users allowed by your subscription many grams are in one mole each Cobalt! Acetoacetate via a mechanism involving acetylketene by Acinetobacter johnsonii -- optimization of fermentation conditions fermentation.. In the acetoacetic ester synthesis or the Knoevenagel condensation metals basis: Expand pages (. -- optimization of fermentation conditions to diethyl malonate in the determination of enantiomeric excess absolute... To the selected substance recent advancements of several catalytic reactions employing well defined metal enolate.. And password, you have to know what substance you are trying to convert to... Vat ( USA ) in this review to show where metal enolate complexes,... Formula VO ( acac ) 2, 8, 15 of several catalytic reactions employing well defined metal complexes... 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